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Physics Lesson 13.1.3 - Temperature and Thermal Equilibrium. The Zeroth Law of Thermodynamics

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Welcome to our Physics lesson on Temperature and Thermal Equilibrium. The Zeroth Law of Thermodynamics, this is the third lesson of our suite of physics lessons covering the topic of Temperature. The Zeroth Law of Thermodynamics, you can find links to the other lessons within this tutorial and access additional physics learning resources below this lesson.

Temperature and Thermal Equilibrium. The Zeroth Law of Thermodynamics

As written in the definition, temperature represents a measure of the ability of an object or a system of objects to transfer heat energy to another object or system. But before explaining what this definition really means, it is necessary to explain a few concepts, such as heat energy, thermal energy, internal energy and heat transfer.

Objects possess energy in a variety of forms. Some types of energy are easily visible and measurable such as kinetic energy, gravitational potential energy and elastic potential energy we have explained earlier in Section 5. However, there are some other types of energy the objects possess in a microscopic form, which are not easy to be identified and calculated. These energies belong to the category of internal energy. The two main subcategories of internal energy are chemical and thermal energy. The first involves the energy generation or absorption during chemical reactions. The later involves the energy generation during the local movements (like vibrations) of objects' particles due to their hotness, as explained earlier. Therefore, it is easy to conclude that thermal energy is somehow related to temperature, i.e. hot objects possess more thermal energy than cold objects as their particles vibrate more rapidly.

The part of this thermal energy that is transferred to another object, is known as heat energy. As explained in the Physics tutorial 5.1 "Work and Energy. Types of Energy", heat can be transferred from one object into another when the proper conditions are created. One condition would be putting a hot and a cold object in contact to each other and thus, paving the way to the heat energy to transfer from the hottest object to the coldest one. There is not any matter transfer during this process; the only thing that is transferred is the heat energy due to the collision pf particles in the bordering parts between the two objects. Faster particles in the outer layer of the hot object collide with the slower particles of the outer layer of the cold object. In this way, the hot object loses some heat energy as its particles get slower during the collision and the cold object gains some heat energy because its particles become faster during the collision with more energetic particles. As a result, there is a heat exchange between objects which eventually bring a change in the internal energy of both objects.

The heat "flow" eventually stops when both objects have reached the same temperature. This means the average speeds of particles vibration in both objects are already equal.

Physics Tutorials: This image provides visual information for the physics tutorial Temperature. The Zeroth Law of Thermodynamics

In other words, the heat flow stops when thermal equilibrium is established. In this way, we obtained the meaning of thermal equilibrium, i.e. a condition in which all parts of a system are at the same temperature.

It is precisely on this concept that the Zeroth Law of Thermodynamics is based. It states that:

If a thermodynamic system A is in thermal equilibrium with another thermodynamic system B and the thermodynamic system B is in thermal equilibrium with a third thermodynamic system C, then the thermodynamic system A is also in thermal equilibrium with the thermodynamic system C.

A thermodynamic system is an object of a group of objects with the same temperature. For simplicity, we will consider the system as a single object. Thus, in simpler words, the Zeroth Law of Thermodynamics says:

If an object A has the same temperature with another object B and the object B has the same temperature with a third object C, then the object A has the same temperature with the object C.

For example, the object in the factory in which a thermometer was originally placed in contact to do its calibration represents the system A, the thermometer itself is the system B and the patient's body is the system C.

The Zeroth Law of Thermodynamics is schematically shown below.

Physics Tutorials: This image provides visual information for the physics tutorial Temperature. The Zeroth Law of Thermodynamics

It is called the "Zeroth Law of Thermodynamics" as it was formulated after the First and the Second Laws of Thermodynamics, for which we will discuss in the next tutorials.

You have reached the end of Physics lesson 13.1.3 Temperature and Thermal Equilibrium. The Zeroth Law of Thermodynamics. There are 3 lessons in this physics tutorial covering Temperature. The Zeroth Law of Thermodynamics, you can access all the lessons from this tutorial below.

More Temperature. The Zeroth Law of Thermodynamics Lessons and Learning Resources

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13.1Temperature. The Zeroth Law of Thermodynamics
Lesson IDPhysics Lesson TitleLessonVideo
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13.1.1The Molecular Meaning of Temperature
13.1.2Units of Temperature
13.1.3Temperature and Thermal Equilibrium. The Zeroth Law of Thermodynamics

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